Integrating Data from Suquıa River Basin: Chemometrics and Other Concepts

BARONI, M.V.; WUNDERLIN D.A.

The Handbook of Environmental Chemistry

SPRINGER

Año: 2017; p. 181 - 200

Assessing the water quality in a river basin seems to be an easy tool.However, some degree of expertise is required when planning and executing several tasks necessary to avoid either excessive or insufficient data. In this chapter we briefly describe some aspect of sampling and sample preparation, which have been discussed in deep in previous chapters. However, after sampling a river, it is necessary to analyse several parameters, arising from many monitoring stations, sampled at different time, etc. All of this generates an amazing database that needs to be carefully explored, looking to extract the most relevant information on changes in the water quality, probable pollution sources, temporal and spatial changes and so on. One simple approximation is the construction of water quality indices from both chemical and biological data, deep discussed in Bistoni et al. (Handb Environ Chem. https://doi.org/10.1007/698_2016_455, 2016) and Ame´ and Pesce (Handb EnvironChem. https://doi.org/10.1007/698_2015_434, 2015). The other way is using multivariate statistics (chemometrics), trying to evidence which changes are occurring, where and when. Here we discuss several chemometrics methods used to verify changes in the water quality of the Suquı´a River basin, starting with non-supervised methods, like cluster analysis (CA), factor analysis (FA, including principal components analysis ? PCA) and going to supervised methods, namely, discriminant analysis (DA) and generalized procrustes analysis (GPA). Although PCA has become the most popular method of analysis for the evaluation of water quality, we think that PCA should be complemented with other methods that help to corroborate results from PCA. In this case, we used CA as a primary tool to evidence spatial differences in the water quality along the basin, confirming these results by PCA, which also added evidence on temporal differences. DA allowed further confirmation of both temporal and spatial changes, with an important data reduction, which is important for the survey of a river basin when the budget is restrictive.Finally, GPA brings further confirmation of other chemometrics methods, enabling a clear differentiation between water quality at diverse river sections, during both dry and rainy season. So far, we truly expect that this chapter helps readers to better design future surveys to evaluate changes of the water quality in other rivers worldwide.