Comparison of the Performance of Chitosan and a Cationic Polyacrylamide as Flocculants of Emulsion Systems.

A.PINOTTI, A.BEVILACQUA , N. ZARITZKY

Journal of Surfactants and Detergents

Springer

Año: 2001 vol. 4 p. 47 - 63

1097-3958

Food industries contribute significantly to the pollution of water streams. Oil in wastewaters must be removed to prevent fouling oi process equipment, to reduce interference with subsequent water-treatment units, and to comply with water-discharge requirements. Polyelectrolytes are frequently used to coagulate and flocculate colloidal systems. A model system of a sunflower oil /water emulsion was used to analyze the effect of: i) emulsion droplet sites, (ii) surfactant chain  length (sodium dodecyl sulfate and sodium tetradecil sulfate), (iii) ionic strength. and iv) pH , on the doses of chitosan (natural cationic polyelectrolyte) and a cationic polyacrylamide, necessary to neutralize electrical charge and to get flocculation. Methods used were: turbidimetry, jar test,colloidal titration, and light microscopy observation. Results showed that the increase of NaCl  concentration reduces the doses of chitosan and polyacrylarnide to reach zero colloidal charge; these doses increase with the surfactant chain length.pH variation did not show any influence on the chitosan dose necessary to flooculate the system. Redispersion of the emulsion  was observed in chitosan and polyacrylarnide treatments.