Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography

REGUERA, MÓNICA; GALANTE, NADIA; VARELA, NOELIA; PROFETA, MARIELA; JORGE, MARÍA; JORGE, LILIAN; ROMERO, JORGE; JORGE, NELLY LIDIA

International Journal of Chemistry Studies

Gupta Publications

Año: 2020 vol. 4 p. 52 - 55

2581-348X

Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied to obtain activation parameters.(H=13.07  0.7 Kcal mol-1; S=-40,28  0.4calmol-1 K-1; G=35.07  0.7 Kcal mol-1) in the 453 ? 553 K temperature range.