Correlation between structural, barrier thermal and mechanical properties of plasticized gelatin film

RIVERO, S.; GARCIA, M.A.; PINOTTI, A.

INNOVATIVE FOOD SCIENCE & EMERGING TECHNOLOGIES

ELSEVIER SCI LTD

Año: 2010 vol. 11 p. 369 - 375

1466-8564

The aims of this work were to develop gelatin films using glycerol as plasticizer (0–100% based on protein mass) and to establish relationships between glycerol content and structural, barrier, thermal and mechanical film properties. These correlations were established since WVP exhibited a minimum for films containing 20 g glycerol/100 g gelatin, while flexibility increased from2.2% to 180.9% and Tg shifted from 137.5 to 21.3 °C, for films without glycerol and plasticized films with 80 g glycerol/100 g gelatin, respectively. Furthermore, a satisfactory fit between Tg experimental data and predicted values by Couchman and Karasz's equationwas found,with glycerol ranging from 0 to 60 g/100 g gelatin. Tg values correlated inversely with film moisture content, and both mechanical and thermal properties showed a strong dependence since elastic modulus and Tg followed a similar trend. Films exhibited similar X-ray patterns regardless of the glycerol concentration, showing a displacement in the position of the peak located at around 2è=8°, which shifted towards lower 2è values with glycerol content. The abovementioned correlations between film physical properties and glycerol content, would allow to select the optimum conditions to develop, process and manage gelatin films according to specific requirements. Industrial relevance: The methodology used in this work is of considerable importance for the film development and could be used in industrial applications. The management of film formulations and the function that each component plays could allow to obtain tailormade films. A series of relationships between film properties based on gelatinwas found, aswell as between these properties and glycerol content of the films. An inflexion point in the behavior and microstructure of these materialswas established due to glycerol concentration. The addition of higher quantities of glycerol than that corresponds to the abovementioned point, would not be recommendable since the properties are not modified and moreover, it is not profitable. These results would allow better management of film formulations and an appropriate selection of plasticizer concentration in accordance with the specific requirements of potential users. films using glycerol as plasticizer (0–100% based on protein mass) and to establish relationships between glycerol content and structural, barrier, thermal and mechanical film properties. These correlations were established since WVP exhibited a minimum for films containing 20 g glycerol/100 g gelatin, while flexibility increased from2.2% to 180.9% and Tg shifted from 137.5 to 21.3 °C, for films without glycerol and plasticized films with 80 g glycerol/100 g gelatin, respectively. Furthermore, a satisfactory fit between Tg experimental data and predicted values by Couchman and Karasz's equationwas found,with glycerol ranging from 0 to 60 g/100 g gelatin. Tg values correlated inversely with film moisture content, and both mechanical and thermal properties showed a strong dependence since elastic modulus and Tg followed a similar trend. Films exhibited similar X-ray patterns regardless of the glycerol concentration, showing a displacement in the position of the peak located at around 2è=8°, which shifted towards lower 2è values with glycerol content. The abovementioned correlations between film physical properties and glycerol content, would allow to select the optimum conditions to develop, process and manage gelatin films according to specific requirements. Industrial relevance: The methodology used in this work is of considerable importance for the film development and could be used in industrial applications. The management of film formulations and the function that each component plays could allow to obtain tailormade films. A series of relationships between film properties based on gelatinwas found, aswell as between these properties and glycerol content of the films. An inflexion point in the behavior and microstructure of these materialswas established due to glycerol concentration. The addition of higher quantities of glycerol than that corresponds to the abovementioned point, would not be recommendable since the properties are not modified and moreover, it is not profitable. These results would allow better management of film formulations and an appropriate selection of plasticizer concentration in accordance with the specific requirements of potential users.