Growth of Open Honeycomb-like Sn Structures on Ag(111) at Low Temperatures

FUHR, J.D.; GAYONE, J.E.; ASCOLANI, H.

JOURNAL OF PHYSICAL CHEMISTRY C

AMER CHEMICAL SOC

Año: 2021 vol. 125 p. 25332 - 25338

1932-7447

We studied, with a combination of low-energy electron diffraction (LEED) and scanning tunneling microscopy (STM) experiments and density functional theory (DFT) calculations, the growth of Sn deposited on the Ag(111) surface kept at low temperatures (<170 K). The LEED experiments show the formation of two phases, a (4 × 4) phase for coverage between 0.17 ML and 0.65 ML and a (7×7)R19° phase that appears at a coverage of ∼0.75 ML. High-resolution STM images for a coverage of 0.37 ML, corresponding to the first phase, show nearly planar islands presenting a local order with a (4 × 4) periodicity. The formed Sn overlayer presents close (triangles) and open honeycomb-like (pentagons and deformed hexagons) structures. DFT calculations show that Sn adatoms should have a high mobility even at low temperatures and that a characteristic of the Sn layer is the coexistence of Sn atoms with three and four neighbors.