Fusing data of different orders for environmental monitoting

ANDRES MARTINEZ BILESIO; ALEJANDRO GARCIA-REIRIZ; BATISTELLI, MARIANELA

ANALYTICA CHIMICA ACTA

ELSEVIER SCIENCE BV

Año: 2019 vol. 1085 p. 48 - 60

0003-2670

In the present work a novel application of data fusion to an environmental monitoring study is proposed. This paper involves the joint analysis of zeroth-, first- and second-order data measured on a particularenvironmental system. The main advantage of this methodology is the possibility of analyzing the relationships of the different order data provided by several analytical techniques. This approach enables toachieve new knowledge, in a way that would be not accessible if considering the information individually.Environmental monitoring databases usually generate large amount of data. Multivariate statistical techniques are necessary to process all this information and obtain a correct interpretation. The Luduena Stream located in Argentina was chosen as the study system. Samples from different sites of the basin were taken periodically. Conductivity and pH (zeroth-order data) were fused with near-infrared (NIR) spectra of suspended particulate material (first-order data) and with fluorescence emission-excitation matrices of dissolved organic matter (second-order data). Different chemometric algorithms made it possible to extract and merge all the information in a new database, enabling its later analysis as a whole. This methodology allowed to successfully studying the behavior of dissolved organic matter together with suspended particulate material and other specific variables, showing links between them. Their distributions along the basin and their evolutions over time were possible to obtain. Therefore, a simpler interpretation to evaluate the system status was achieved. This model allowed differentiating the variables affected by anthropic activities from those with a natural origin.