IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Iodine-Catalyzed Iso-Nazarov Cyclization of Conjugated Dienals for the Synthesis of 2-Cyclopentenones
Autor/es:
MARSILI, LUCÍA A.; RIVEIRA, MARTÍN J.; PERGOMET, JORGELINA L.; GANDON, VINCENT
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2018 vol. 20 p. 7298 - 7303
ISSN:
1523-7060
Resumen:
Molecular iodine was identified as an efficient catalyst for the cycloisomerization of conjugated dienals to substituted 2-cyclopentenones. DFT calculations suggested an unexpected concerted character for this cyclization.
