IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films
Autor/es:
MARÍA MAGIONE, ROLANDO SPANELLO; DANIELA MINUDRI, DANIEL HEREDIA, LUCIANA FERNÁNDEZ, LUIS OTERO, FERNANDO FUNGO; MARÍA MAGIONE, ROLANDO SPANELLO; DANIELA MINUDRI, DANIEL HEREDIA, LUCIANA FERNÁNDEZ, LUIS OTERO, FERNANDO FUNGO
Revista:
ELECTROCHIMICA ACTA
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2016 vol. 207 p. 143 - 151
ISSN:
0013-4686
Resumen:
A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.
