IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Synthesis of a simple chiral auxiliary derived from levoglucosenone
Autor/es:
MARÍA M. ZANARDI; ALEJANDRA G. SUÁREZ
Revista:
TETRAHEDRON LETTERS
Editorial:
Elsevier
Referencias:
Lugar: Oxford; Año: 2009 vol. 50 p. 999 - 1002
ISSN:
0040-4039
Resumen:
The synthesis of a chiral alcohol derived from levoglucosenone has been studied. The alcohol was employed as chiral template in an asymmetric DielsAlder reaction of the corresponding acrylic ester derivative with cyclopentadiene, and was shown to be an efficient asymmetric inductor. The oxidation reaction detected during the hydrogenation of a secondary allylic alcohol intermediate with Pd/C was also investigated.
