IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Evaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols
Autor/es:
ARIEL M. SAROTTI; PABLO L. PISANO; SILVINA C. PELLEGRINET
Revista:
ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ARKAT USA INC
Referencias:
Año: 2011 vol. 7 p. 343 - 357
ISSN:
1551-7004
Resumen:
The use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of isomeric mixtures of bicyclic and monocyclic secondary cyclohexenols was investigated. Synthesis, NMR and conformational analyses of the derivatives were performed and Gauge-Independent Atomic Orbital (GIAO) 1H NMR Boltzmann weighted average chemical shifts were computed. The studied methodology proved to be of practical value for most of the systems under study.
