Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization

PICCHIO, MATÍAS L.; BARANDIARAN, MARÍA J.; PICCHIO, MATÍAS L.; BARANDIARAN, MARÍA J.; BOHÓRQUEZ, SILFREDO J.; GUGLIOTTA, LUIS M.; BOHÓRQUEZ, SILFREDO J.; GUGLIOTTA, LUIS M.; VAN DEN BERG, PETER G.C.A.; MINARI, ROQUE J.; VAN DEN BERG, PETER G.C.A.; MINARI, ROQUE J.

INDUSTRIAL & ENGINEERING CHEMICAL RESEARCH

AMER CHEMICAL SOC

Lugar: Washington; Año: 2016 p. 10271 - 10277

0888-5885

Over the last few years casein-based latexes have attracted increasing interest because of their good film-forming properties. This paper investigates the use of acrylic/casein hybrid latexes with a solids content of 35% in a coating application, which involves the evaluation of non-formulated latexes as binders, the high-throughput formulation with different commercial agents (cosolvents, wetting agents and defoamers) and the formulation optimization using statistic multivariable analysis. Latexes were obtained by emulsifier-free emulsion polymerization of acrylic monomers in the presence of a chemically modified casein containing 10 vinyl bonds per molecule. The optimized clear coats formulated from the hybrid latexes showed a good performance requiring a reduced formulation-agents concentration, which could be an important benefit from environmental viewpoint. Together the above results demonstrate that the casein bio-based latexes represent a promising alternative for the development of a new generation of ecological binders.