INCAPE   05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Gas-phase upgrading of biomass-derived 2-hexanol to liquid transportation fuels on Cu-based mixed oxides.
Autor/es:
APESTEGUÍA, CARLOS RODOLFO; LUGGREN, PABLO JORGE; DI COSIMO, JUANA ISABEL
Lugar:
Beijing
Reunión:
Congreso; 16th International Congress on Catalysis (ICC 16); 2016
Institución organizadora:
The International Association of Catalysis Societies
Resumen:
The gas-phase synthesis of high molecular weight compounds of application as liquid transportation fuels from 2-hexanol was studied on Cu-Mg-Al mixed oxides with different copper content (Z: 0.3-61.2%) and a Mg/Al =1.5 molar ratio. Catalysts were prepared by coprecipitation and characterized by several techniques such as BET surface area, XRD, TPD of CO2, TPR and N2O decomposition. Cu-Mg-Al mixed oxides are active and selective for the upgrading of 2-hexanol toward liquid fuels, i.e., C9-C18+ compounds with low oxygen content. Catalyst activity and selectivity depend on Z, as well as the quality of the products and the kind of reaction mechanism leading to them.