Catalyst formulation to avoid reaction runaway during diesel soot combustion

MARÍA ARIELA PERALTA; MARTÍN SEBASTIÁN GROSS; MARÍA ALICIA ULLA; CARLOS ALBERTO QUERINI

APPLIED CATALYSIS A-GENERAL

ELSEVIER SCIENCE BV

Año: 2009 vol. 367 p. 59 - 69

0926-860X

Soot combustion is a highly exothermic reaction. The aim of this work is to demonstrate that catalyst overheating by reaction runaway can be moderated by the proper selection of a catalyst support, La2O32O3 being a good choice for this purpose. In K/La2O3 catalysts, lanthanumcompounds decompose in the same temperature range in which soot combustion occurs, thus absorbing part of the heat released in the combustion process and avoiding the reaction runaway. Taking into account this property of catalysts supported on La2O3, the catalytic behavior of K/La2O3 and K/CeO2 was compared under reaction conditions in which a reaction runaway could occur. Catalytic activity was followed by temperatureprogrammed oxidation, and the heats evolved were measured by differential scanning calorimetry. Catalysts were characterized by BET, XRD, DSC and FTIR. Tight and loose contact between catalyst and soot was analyzed, and the effect of NO in the gas phase was studied.2O3 catalysts, lanthanumcompounds decompose in the same temperature range in which soot combustion occurs, thus absorbing part of the heat released in the combustion process and avoiding the reaction runaway. Taking into account this property of catalysts supported on La2O3, the catalytic behavior of K/La2O3 and K/CeO2 was compared under reaction conditions in which a reaction runaway could occur. Catalytic activity was followed by temperatureprogrammed oxidation, and the heats evolved were measured by differential scanning calorimetry. Catalysts were characterized by BET, XRD, DSC and FTIR. Tight and loose contact between catalyst and soot was analyzed, and the effect of NO in the gas phase was studied.2O3, the catalytic behavior of K/La2O3 and K/CeO2 was compared under reaction conditions in which a reaction runaway could occur. Catalytic activity was followed by temperatureprogrammed oxidation, and the heats evolved were measured by differential scanning calorimetry. Catalysts were characterized by BET, XRD, DSC and FTIR. Tight and loose contact between catalyst and soot was analyzed, and the effect of NO in the gas phase was studied.