INCAPE   05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
artículos
Título:
Study of the synthesis of CeO2 nanoparticles for their use in CO preferential oxidation (COPrOx)
Autor/es:
LEONARDO PEIRETTI; INES TISCORNIA; EDUARDO E. MIRÓ
Revista:
CHEMICAL ENGINEERING JOURNAL
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2013 vol. 223 p. 507 - 515
ISSN:
1385-8947
Resumen:
CeO2 nanoparticles were synthesized by the controlled precipitation method from a Ce(NO3)3 solution. To
this end, two additives were used alternatively: ethylene glycol (EG) and tetramethylammonium hydroxide
(TMAH). Their function was to reduce the particle size obtained after the synthesis. After precipitation
and drying, nitrate and organic residuals must be removed, and the method employed for this step could
affect the structure and size of the particles. This is an important issue for achieving contaminant-free
measurements in catalytic tests. In order to optimize the residuals removing process, a thorough study
of the species present and/or eliminated was carried out. Our findings show that a calcination temperature
of at least 500 C is necessary in order to accomplish the complete removal of solvent and precursors
such as NO3 . Among the catalysts studied, the one prepared with EG showed the best activity for CO preferential
oxidation. In order to study the effect of the residuals upon the catalytic activity, samples prepared
using EG were calcined at different temperatures and tested for the COPrOx reaction. CO
conversions for all the samples were between 80% and 93% at different temperatures. The best activity
was obtained with the sample calcined at 500 C, which is in agreement with the minimum temperature
necessary for the total elimination of residuals.