The role of Pd–In interactions on the performance of PdIn-Hmordenite in the SCR

HERNÁN DECOLATTI, HANNA SOLT, FERENC LÓNYI, JÓZSEF VALYON, EDUARDO MIRÓ, LAURA GUTIERREZ

CATALYSIS TODAY

ELSEVIER SCIENCE BV

Año: 2011 vol. 172 p. 124 - 131

0920-5861

The aims of this work were to use several techniques to characterize the generated species when indium and palladium were successively exchanged in H-mordenite and to investigate the effect of the Pd/In ratio on the said species as well as to correlate the activity of the prepared solids with the formed moieties. We studied the activity of In-Hmordenite catalysts obtained by reductive solid-state ion exchange and the effect of the addition of Pd. There was a clear correlation between the maximum catalytic activity of each catalyst and its ability to form NO2 in the temperature-programmed desorption of NO (NOTPD) experiments performed after NO adsorption. PdInHM(1/3) was the catalyst that showed the best results in activity and, after the first catalytic test, it was further activated. The temperature-programmed reduction (TPR) and NO-TPD results of this solid suggest that the amount of active species increased after the reaction and that there would be some kind of Pd–In interaction. The characterization of the fresh and used samples by CO adsorption and FTIR shows the differences between PdInHM(1/3) and PdInHM(1/6) catalysts in terms of how Pd was present on the support, and justifies the different catalytic behavior of both catalysts.