INCAPE 05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
artículos
Título:
A High (Z)/(E) Ratio Obtained During the 3-Hexyne Hydrogenation with a Catalyst Based on a Rh(I) Complex Anchored on a Carbonaceous Support
Autor/es:
LIPRANDI, D.A.; CAGNOLA, E.A.; PAREDES, J. F.; BADANO, J.M.; QUIROGA , M.E.
Revista:
CATALYSIS LETTERS
Editorial:
SPRINGER
Referencias:
Lugar: Netherlands; Año: 2012 vol. 142 p. 231 - 237
ISSN:
1011-372X
Resumen:
The (Z)/(E) ratio was analyzed for the 3-hexyne semi-hydrogenation at 275, 290 and 303 K. [RhCl(NH2 (CH2)12CH3)3] pure and supported on a carbonaceous material were used as catalysts. The supported complex showed high values of conversion and selectivity, and its behaviour was much better than the Lindlar catalyst used as a reference.
