INVESTIGADORES
WILLIAMS Federico Jose
artículos
Título:
Sulfur, normally a poison, strongly promotes chemoselective catalytic hydrogenation: stereochemistry and reactivity of crotonaldehyde on clean and S-modified Cu(111)
Autor/es:
MAY E. CHIU; GEORGIOS KYRIAKOU; FEDERICO J. WILLIAMS; DAVID J. WATSON; MINTCHO S. TIKHOV; RICHARD M. LAMBERT
Revista:
CHEMICAL COMMUNICATIONS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Año: 2006 p. 1283 - 1285
ISSN:
1359-7345
Resumen:
Sulphur adatoms strongly activate the otherwise inert Cu(111) surface towards chemoselective hydrogenation of crotonaldehyde by electronically perturbing and strongly tilting the reactant.
