INVESTIGADORES
SUAREZ Sebastian
artículos
Título:
N-butyl pyridinium undecachloro?carbadodecaborate structure and its comparison with similar compounds
Autor/es:
SEBASTIAN SUAREZ; MARIA ANA FOI; SHAWN EADY; ANNA LARSEN; FABIO DOCTOROVICH
Revista:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Editorial:
WILEY-BLACKWELL PUBLISHING, INC
Referencias:
Lugar: Londres; Año: 2011 vol. C67 p. 417 - 417
ISSN:
0108-2701
Resumen:
The title compound, C9H14N+CHB11Cl11 , was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkylpyridinium and dialkylimidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butylpyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds.
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