Reactivity and Structure of Complexes of Small Molecules: Nitric oxide and Nitrous Oxide

OLABE, J. A.; SLEP, L. D.

Comprehensive Coordination Chemistry II

Elsevier Science Limited

Lugar: Oxford; Año: 2004; p. 603 - 623

3.3 NO and N2O COMPLEXES   3.3.1 Structure and Bonding 3.3.1.1 General Properties of NO, Bonding Models and the Enemark-Feltham Formalism 3.3.1.2 Solid-State Structures of ¥ç1-NO Mononuclear Nitrosyls. Coordination Numbers 6, 5, 4 and Others. Spectroscopic Characterization 3.3.1.3  Polynitrosyls, Bridging Nitrosyls and Clusters 3.3.1.4  ¥ç1-ON (Isonitrosyls) and ¥ç2-NO Complexes 3.3.1.5  N2O Complexes 3.3.2 Synthesis and Reactivity of NO and N2O Complexes 3.3.2.2.1 Reactions of NO 3.3.2.1.1 Synthesis of NO Complexes 3.3.2.1.2 Formation and Dissociation Reactions 3.3.2.1.3 Nucleophilic Additions 3.3.2.1.4 Reduction: Chemistry and Electrochemistry 3.3.2.1.5 Reductive Nitrosylation 3.3.2.1.6 Electrophilic Reactions 3.3.2.1.7 Disproportionation of Bound NO 3.3.2.1.8 Nitrosyl Transfer 3.3.2.2 Reactions of N2O 3.3.2.2.1 Synthesis of N2O Complexes 3.3.2.2.2 Reduction of N2O through O-Atom Transfer 3.3.2.2.3 N¨¬N Bond Cleavage 3.3.2.2.4 N2O Formed through N-Atom Transfer 3.3.2.2.5 N2O from Reductive Coupling of NO 3.3.2.2.6 Catalyzed Disproportionation of NO in Basic Medium 3.3.2.2.7 Electroreduction Catalyzed by Transition Metal Complexes 3.3.3 Conclusions and Outlook