First example of a preferred anti configuration in RN=SX2 compounds: N-Fluoromyliminotrifluoromethylsulfur Fluoride, FC(O)N=S(F)CF3

ROSANA M. ROMANO; CARLOS O. DELLA VÉDOVA; MARTA MORA VALDÉZ; EDGARDO H. CUTÍN

JOURNAL OF RAMAN SPECTROSCOPY

Año: 2000 vol. 31 p. 881 - 885

0377-0486

The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms. N atoms. N atoms. lone pair and the second is related to the C O double bond with respect to the N S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. N atoms.