Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]

LUCIANA C. JUNCAL; EVELINA G. FERRER; PATRICIA A. M. WILLIAMS; ROLAND BOESE; C. GUSTAVO POZZI; CARLOS O. DELLA VÉDOVA; ROSANA M. ROMANO

CHEMICAL PHYSICS LETTERS

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2022 vol. 794

0009-2614

Single crystals of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH 3 CH 2 CH 2 OC(S)S) 2 (C 5 H 5 N) 2 ], have been prepared and studied using single crystal X-ray diffraction method and IR spectroscopy. The crystal structure of tetracoordinated Ni(II) xanthate complex, bis(O-propyldithiocarbonato)nickel(II), [Ni(CH 3 CH 2 CH 2 OC(S)S) 2 ], was also determined and compared with the previously reported structure. The existence of a cis form for a hexacoordinated species of the [NiS 4 N 2 ] type is infrequent for this family of complexes.