INVESTIGADORES
SCHULZ Erica Patricia
artículos
Título:
Colloidal properties of amiodarone in water at low concentration
Autor/es:
LUCIANO BENEDINI; PAULA V. MESSINA; RUBEN H. MANZO; DANIEL A. ALLEMANDI; SANTIAGO D. PALMA; ERICA P. SCHULZ; MARISA A. FRECHERO; PABLO C. SCHULZ
Revista:
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Editorial:
ACADEMIC PRESS INC ELSEVIER SCIENCE
Referencias:
Año: 2009 p. 407 - 414
ISSN:
0021-9797
Resumen:
Amiodarone aqueous systems at concentrations C 6 3 mg/mL were studied with different techniques
(conductivity, solubility, ion-selective electrodes, pH, viscosity, polarizing microscopy, computational
simulation, electron microscopy and fluorescence at various temperatures. The Krafft point
(TK = 70.6 C) was determined. A partial phase diagram was plotted showing the critical micelle concentration
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(conductivity, solubility, ion-selective electrodes, pH, viscosity, polarizing microscopy, computational
simulation, electron microscopy and fluorescence at various temperatures. The Krafft point
(TK = 70.6 C) was determined. A partial phase diagram was plotted showing the critical micelle concentration
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(conductivity, solubility, ion-selective electrodes, pH, viscosity, polarizing microscopy, computational
simulation, electron microscopy and fluorescence at various temperatures. The Krafft point
(TK = 70.6 C) was determined. A partial phase diagram was plotted showing the critical micelle concentration
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
C 6 3 mg/mL were studied with different techniques
(conductivity, solubility, ion-selective electrodes, pH, viscosity, polarizing microscopy, computational
simulation, electron microscopy and fluorescence at various temperatures. The Krafft point
(TK = 70.6 C) was determined. A partial phase diagram was plotted showing the critical micelle concentration
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
TK = 70.6 C) was determined. A partial phase diagram was plotted showing the critical micelle concentration
(CMC) dependence on temperature, the solubility and a transition between a coacervate and an
unstable gel below TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
TK as a function of temperature. The nature of aggregates below TK at different concentrations
was determined. Micellization is an entropy-driven process which is probably caused by a
strong dehydration of the amiodarone backbone on micellization. CMC, micelle aggregation number
and TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
work.
work.
TK given in earlier literature were misinterpreted in the original articles and are re-interpreted in this
work.
2009 Elsevier Inc. All rights reserved.2009 Elsevier Inc. All rights reserved.