Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors

PICCHIO, MATÍAS L.; MINUDRI, DANIELA; MANTIONE, DANIELE; CRIADO-GONZALEZ, MIRYAM; GUZMÁN-GONZÁLEZ, GREGORIO; SCHMARSOW, RUTH; MÜLLER, ALEJANDRO J.; TOMÉ, LILIANA C.; MINARI, ROQUE J.; MECERREYES, DAVID

ACS Sustainable Chemistry and Engineering

American Chemical Society

Año: 2022 vol. 10 p. 8135 - 8142

Natural deep eutectics solvents (NADES), owing to their high solvation capacity and nontoxicity, are actively being sought for many technological applications. Herein, we report a series of novel NADES based on choline chloride and plant-derived polyphenols. Most of the obtained phenolic NADES have a wide liquid range and high thermal stability above 150 °C. Among them, small-sized polyphenols, like pyrogallol, vanillyl alcohol, or gentisic acid, lead to low-viscosity liquids with ionic conductivities in the order of 10-3S cm-1at room temperature. Interestingly, polyphenols possess valuable properties as therapeutic agents, antioxidants, adhesives, or redox-active compounds, among others. Thus, we evaluated the potential of these novel NADES for two applications: bioadhesives and corrosion protection. The mixture of choline chloride-vanillyl alcohol (2:3 mol ratio) and gelatin resulted in a highly adhesive viscoelastic liquid (adhesive stress ≈ 135 kPa), affording shear thinning behavior. Furthermore, choline chloride-tannic acid (20:1) showed an extraordinary ability to coordinate iron ions, reaching excellent corrosion inhibitive efficiencies in mild steel protection.