Luminescence and electrical properties of single ZnO/MgO core/shell nanowires

GRINBLAT, GUSTAVO; BERN, FRANCIS; BARZOLA-QUIQUIA JOSÉ; TIRADO, MONICA; COMEDI, DAVID; ESQUINAZI, PABLO

APPLIED PHYSICS LETTERS

AMER INST PHYSICS

Lugar: New York; Año: 2014 p. 103113 - 103114

0003-6951

To neutralise the influence of the surface of ZnO nanowires for photonics and optoelectronicapplications, we have covered them with insulating MgO film and individually contacted them for electrical characterisation. We show that such a metal-insulator-semiconductor-type nanodevice exhibits a high diode ideality factor of 3.4 below 1V. MgO shell passivates ZnO surface states and provides confining barriers to electrons and holes within the ZnO core, favouring excitonic ultraviolet radiative recombination, while suppressing defect-related luminescence in the visible and improving electrical conductivity. The results indicate the potential use of ZnO/MgO nanowires as a convenient building block for nano-optoelectronic devices.