INVESTIGADORES
LIZARRAGA Leonardo
congresos y reuniones científicas
Título:
Electrochemical Promotion of Propane Combustion on Highly Dispersed Pt Nanoparticles
Autor/es:
A. KAMBOLIS; L. LIZARRAGA; M.N. TSAMPAS; M. RIEU; J.-P. VIRICELLE; P. VERNOUX
Lugar:
Seattle
Reunión:
Encuentro; 221th Electrochemical Society Meeting; 2012
Institución organizadora:
Electrochemical Society
Resumen:
Pt nanoparticles, in a size range which varies from 3 to 20 nm, were dispersed in the porosity of a 7.5 µm-thick layer of LSCF-GDC electrode interfaced on a dense GDC membrane. Small positive polarizations (200 µA / 0.8V - 1.2V) can strongly increase the Pt nanoparticles catalytic performance for propane deep oxidation at low temperatures (267°C-338°C). 40%-enhancement of the propane conversion was achieved with apparent Faraday efficiency values up to 85. These results clearly demonstrate that metallic nanoparticles dispersed in the porosity of a mixed ionic electronic conducting electrode can be electropromoted.