OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE ON ACTIVATED CARBONS DERIVED FROM A NATIVE WOOD AS CATALYST

JORGE DE CELIS; SOLEDAD VILLAVERDE; ANA LEA CUKIERMAN; NORMA AMADEO

LATIN AMERICAN APPLIED RESEARCH

PLAPIQUI(UNS-CONICET)

Lugar: Bahia Blanca; Año: 2009 vol. 39 p. 165 - 171

0327-0793

Activated carbons were developed by phosphoric acid activation of a native wood (Pro-sopis ruscifolia) under a self-generated atmosphere or flowing air. Their potentiality as catalyst for oxi-dative dehydrogenation of ethylbenzene to styrene was examined at pre-established operating condi-tions. The carbons developed in the self-generated atmosphere showed specific surface area of 2281 m2/g and total pore volume of 1.7 cm3/g, whereas values of 1638 m2/g and 1.3 cm3/g, respectively, char-acterized those obtained in air. A commercial acti-vated carbon (1200 m2/g and 0.7 cm3/g) was also used for comparison. Both wood-derived carbons resulted potentially suitable as catalyst for ethylbenzene oxi-dative dehydrogenation. Nevertheless, those devel-oped in the self-generated atmosphere showed a bet-ter catalytic performance than the carbons obtained in air and the commercial sample. The behaviour could be due to its lower microporosity compared with the commercial sample, and to the formation of oxidative condensation products during the oxidative dehydrogenation of ethylbenzene with greater con-tent of carbonyl groups than for the sample activated under flowing air. Chemical and textural characteri-zation of the used carbons conclusively evidenced the presence of oxidative condensation products pointing to formation of new active surfaces.