INVESTIGADORES
MERINO Nora Andrea
artículos
Título:
Effect of the calcium on the textural, structural and catalytic properties of La1-xCaxCo1-yFeyO3 perovskites
Autor/es:
NORA ANDREA MERINO; BIBIANA PATRICIA BARBERO; CAROLINE CELLIER; JULIO ANDRADE GAMBOA; LUIS EDUARDO CADÚS
Revista:
CATALYSIS LETTERS
Editorial:
SPRINGER
Referencias:
Año: 2007 vol. 113 p. 130 - 140
ISSN:
1011-372X
Resumen:
In La1-x Ca x Co1-y Fe y O3 perovskites, the calcium substitution modifies the crystalline structure toward a pseudocubic one and produces an electronic unbalance, compensated by the formation of oxygen vacancies and Fe4+ ions. It also increases slightly the ethanol conversion in total combustion, compensating the detriment of catalytic activity caused by the iron substitution and it increases notably the selectivity to total oxidation.
