INVESTIGADORES
RADIVOY gabriel Eduardo
artículos
Título:
A new and efficient methodology for olefin epoxidation catalyzed by supported cobalt nanoparticles
Autor/es:
L. ROSSI FERNÁNDEZ; V. DORN; G. RADIVOY
Revista:
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Editorial:
BEILSTEIN-INSTITUT
Referencias:
Año: 2021 vol. 17 p. 519 - 526
ISSN:
1860-5397
Resumen:
A new heterogeneous catalytic system consisting of cobalt nanoparticles (CoNPs) supported on MgO and tert-butylhydroperoxide (TBHP) as oxidant is presented. This CoNPs@MgO/tBuOOH catalytic combination allowed the epoxidation of a variety of olefins with good to excellent yield and high selectivity. The catalyst preparation is simple and straightforward from commercially available starting materials and it could be recovered and reused maintaining unaltered its high activity.
