INVESTIGADORES
RADIVOY gabriel Eduardo
artículos
Título:
Reduction of Hydrazines, Azo and Azoxy compounds, and Amine N-Oxides with the NiCl2.2H2O-Li-DTBB (cat.) Combination
Autor/es:
F. ALONSO; G. RADIVOY; M. YUS
Revista:
TETRAHEDRON
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Año: 2000 vol. 56 p. 8673 - 8678
ISSN:
0040-4020
Resumen:
The NiCl2´2H2O/Li/DTBB (10 mol%) combination allows the reduction of aromatic hydrazines 1 (to amines), azo compounds 2 (to primary amines), azoxy compounds 3 (to azo compounds or to primary amines, depending on the reaction conditions) or amine N-oxides 4 (to tertiary amines), under mild reaction conditions (THF, room temperature).2´2H2O/Li/DTBB (10 mol%) combination allows the reduction of aromatic hydrazines 1 (to amines), azo compounds 2 (to primary amines), azoxy compounds 3 (to azo compounds or to primary amines, depending on the reaction conditions) or amine N-oxides 4 (to tertiary amines), under mild reaction conditions (THF, room temperature).
