INVESTIGADORES
ESTRIN Dario Ariel
artículos
Título:
Transnitrosation of Nitrosothiols: characterization of an elusive intermediate
Autor/es:
LAURA PERISSINOTTI,; A. G. TURJANSKI; D. A. ESTRIN; F. DOCTOROVICH
Revista:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Editorial:
American Chemical Society
Referencias:
Lugar: Columbus, OH, USA; Año: 2005 vol. 127 p. 486 - 487
ISSN:
0002-7863
Resumen:
We report an investigation of the reaction between (S)-nitroso-L-cysteine ethyl ester and L-cysteine ethyl ester as a model of physiologically relevant transnitrosation processes. Our theoretical and experimental evidence clearly supports the existence of a nitroxyl disulfide intermediate in solution.
