INVESTIGADORES
DOCTOROVICH Fabio Ariel
artículos
Título:
Transnitrosation of Nitrosothiols: Characterization of an Elusive Intermediate
Autor/es:
L. PERISSINOTTI; A. TURJANSKI; D. ESTRIN; F. DOCTOROVICH
Revista:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Editorial:
ACS
Referencias:
Año: 2005 vol. 127 p. 486 - 487
ISSN:
0002-7863
Resumen:
We report an investigation of the reaction between (S)-nitroso-L-cysteine ethyl ester and L-cysteine ethyl ester as a model of physiologically relevant transnitrosation processes. Our theoretical and experimental evidence clearly supports the existence of a nitroxyl disulfide intermediate in solution.
