INVESTIGADORES
DOCTOROVICH Fabio Ariel
artículos
Título:
NO+, NO●, NO?! Nitrosyl Siblings from [IrCl5(NO)]?
Autor/es:
ESCOLA, N; BIKIEL, D. E.; BAGGIO, R.; DI SALVO, F; DOCTOROVICH, F.
Revista:
INORGANICA CHIMICA ACTA
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2011 vol. 374 p. 528 - 539
ISSN:
0020-1693
Resumen:
Pentachloronitrosyliridate(III) ([IrCl5(NO)]), the most electrophilic NO+ known to date, can be reduced chemically and/or electrochemically by one or two electrons to produce the NO and HNO/NO forms. The nitroxyl complex can be formed either by hydride attack to the NO+ in organic solvent, or by decomposition of iridium-coordinated nitrosothiols in aqueous solutions, while NO is produced electrochemically or by reduction of [IrCl5(NO)] with H2O2. Both NO and HNO/NO complexes are stable under certain conditions but tend to labilize the trans chloride and even the cis ones after long periods of time.As expected, the NO+ is practically linear, although the IrNO moiety is affected by the counterions due to dramatic changes in the solid state arrangement. The other two nitrosyl redox states comprise bent structures.
