INVESTIGADORES
DOCTOROVICH Fabio Ariel
artículos
Título:
Structural characterization of the water-soluble porphyrin complexes [FeII(TPPS) (NO•)]4─ and [μ-O-([FeIII(TPPS)])2]8─
Autor/es:
MAZZEO, AGOSTINA; GAVIGLIO, CARINA; PELLEGRINO, JUAN; DOCTOROVICH, FABIO
Revista:
Heliyon
Editorial:
Elsevier Ltd
Referencias:
Año: 2022 vol. 8
ISSN:
2405-8440
Resumen:
Iron water-soluble porphyrins have been long used as biomimetic compounds for modelling the active sites found in heme-enzymes. In this regard, the anionic porphyrin [FeIII(TPPS)]3─ and its coordination complexes have been repeatedly chosen as suitable water-soluble platforms for bioinorganic chemistry studies. In this work we report for the first time the crystal structure of the water-soluble nitrosyl complex [FeII(TPPS) (NO)]4─ along with that of oxodimeric ferric species [μ-O-([FeIII(TPPS)])2]8─.
