INVESTIGADORES
CIOLINO Andres Eduardo
artículos
Título:
Synthesis and Characterization of Model Diblock Copolymers of Poly(dimethylsiloxane) with Poly(butadiene)-1,4 or Poly(ethylene)
Autor/es:
ANDRÉS CIOLINO; DIMITRIS PANTAZIS; GIORGOS SAKELLARIOU; MARCELO VILLAR; ENRIQUE VALLÉS; NIKOS HADJICHRISTIDIS
Revista:
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Editorial:
John Wiley & Sons
Referencias:
Año: 2006 vol. 2006 p. 1579 - 1590
ISSN:
0887-624X
Resumen:
Model diblock copolymers of polybutadiene-1,4 (PB) and poly(dimethylsiloxane) (PDMS), PB-b-PDMS, were synthesized by the sequential anionic polymerization (high vacuum techniques) of butadiene and hexamethylciclotrisiloxane (D3). By homogeneous hydrogenation of PB-b-PDMS, the corresponding poly(ethylene) and poly(dimethylsiloxane) block copolymers, PE-b-PDMS, were obtained.The synthesized block copolymers were characterized by nuclear magnetic resonance
