Relativistic correction of the generalized oscillator strength sum rules

RODOLFO H. ROMERO; GUSTAVO A. AUCAR

PHYSICAL REVIEW A - ATOMIC, MOLECULAR AND OPTICAL PHYSICS

AMER PHYSICAL SOC

Lugar: New York; Año: 1998 vol. 57 p. 2212 - 2215

1050-2947

A complete and accurate scheme to calculate relativistic corrections to the generalized oscillator strength sum rules is presented. We discuss the relations between ours and previous schemes used to solve this old problem. A calculation of the relativistic correction to the sum rule S2 , up to the order (v/c)2, is given. Our method could also be used to calculate relativistic corrections of molecular properties.