“Effect of MgO activation conditions on its catalytic properties for base-catalyzed reactions”

V.K. DÍEZ; C.A. FERRETTI; P.A. TORRESI; C.R. APESTEGUÍA; J.I. DI COSIMO

CATALYSIS TODAY

ELSEVIER SCIENCE BV

Año: 2011 vol. 271 p. 21 - 27

0920-5861

The effect of the MgO calcination temperature on its basicity and catalytic properties was studied.  Three MgO samples calcined at 673, 773 and 873 K (samples MgO-673, MgO-773 and MgO-873) were characterized by different physical and spectroscopic techniques.  The surface base properties were probed by temperature-programmed desorption of CO2 and infrared spectroscopy after CO2 adsorption at 298 K and sequential evacuation at increasing temperatures.  The dimensions of face-centered cubic unit cell for MgO samples decreased while crystallinity and mean crystallite size increased with calcination temperature.  MgO samples contained surface sites of strong (low coordination O2- anions), medium (oxygen in Mg2+-O2- pairs) and weak (OH- groups) basicity. The density of strong basic sites was predominant on MgO-673, but decreased with the calcination temperature together with the density of OH- groups; on the contrary, the density of Mg2+-O2- pair sites increased with calcination temperature.  The catalytic properties of  MgO samples were explored for the cross-aldol condensation of citral with acetone to obtain pseudoionones (PS), the transesterification of methyl oleate with glycerol to yield monoglycerides (MG), and the gas-phase hydrogen transfer reaction of mesityl oxide with 2-propanol to form 4-methyl-3-penten-2ol (UOL).  The initial PS and MG formation rates decreased with calcination temperature following a trend similar to the density of strong basic sites which suggested that the rate limiting steps for both reactions involve coordinatively unsaturated O2- active sites. In contrast, the initial UOL formation rate in mesityl oxide/2-propanol reaction increased with MgO calcination temperature following the same trend as medium-strength basic sites, thereby indicating that Mg2+-O2− pairs promote the formation of the six-atom cyclic intermediate needed in the Meerwein–Ponndorf–Verley mechanism.