INVESTIGADORES
VAZQUEZ marcela Vivian
congresos y reuniones científicas
Título:
CONCRETE RESISTIVITY MEASUREMENTS AS AN ESTIMATE FOR CHLORIDE-INDUCED CORROSION
Autor/es:
W. MORRIS; , A. VICO; M. VAZQUEZ
Lugar:
Dusseldorf, Alemania
Reunión:
Conferencia; 53rd. Meeting of the International Society of Electrochemistry; 2002
Resumen:
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It is widely accepted that chloride ions are
responsible for causing local passive layer breakdown and subsequent corrosion
of reinforcing steel bars (rebars) in concrete. There is general agreement in
the existence of a certain Cl- concentration threshold value (ClTH)
necessary to initiate the corrosion process. The ClTH may vary depending on concrete mix properties such as
cement type, C3A content, blended materials, water to cement ratio,
temperature, relative humidity, and the exposure conditions and source of
chloride penetration, among others.
Further than this one more question arises
that needs a practical answer: how to
determine this value be for a given structure in a particular environment.
From our previous investigations [1,2], we
have, correlated the evolution of Ecorr
and the corrosion current density icorr, the values of r and the Cl-concentration at the rebar surface as a function
of time by plotting the Cl- concentration as a funtion of concrete
resistivity (r) determined for a given time. The ClTH value considered
here was the Cl- ions concentration at the rebar surface
corresponding to an active state of corrosion (Ecorr < -0.35 V vs. CSE and
icorr > 0.2 mAcm-2).
Two separated regions appear: the active
corrosion area and the passive corrosion area. The limit between these would
represent the correlation between ClTH values and concrete
resistivity which can be expressed by the following expression
ClTH = 0,009 r + 0,33
Thus, given a certain structure, the risk
for Cl- induced corrosion can be
estimated by measuring the
resistivity of concrete, which in turn, implies using a simple non-destructive
technique requiring neither expensive nor sophisticated instruments.