Developing Post-Consumer Recycled Flexible Polypropylene and Fumed Silica-Based Nanocomposites with Improved Processability and Thermal Stability

E. VELAZQUEZ; C. PATIÑO VIDAL; G. COPELLO; C. LOPEZ DICASTILLO; C. J. PÉREZ; A. GUARDA; M.J. GALOTTO

polymers

MDPI

Lugar: BASEL; Año: 2023 vol. 15 p. 1142 - 1158

2073-4360

Collection and mechanical recycling of post-consumer exible polypropylene packaging islimited, principally due to polypropylene being very light-weight. Moreover, service life and thermal–mechanical reprocessing degrade PP and change its thermal and rheological properties according to the structure and provenance of recycled PP. This work determined the effect of incorporating two fumed nanosilica (NS) types on processability improvement of post-consumer recycled exible polypropylene (PCPP) through ATR-FTIR, TGA, DSC, MFI and rheological analysis. Presence of trace polyethylene in the collected PCPP increased the thermal stability of the PP and was signicantly maximized by NS addition. The onset decomposition temperature raised around 15 ◦C when 4 and 2 wt% of a non-treated and organically modied NS were used, respectively. NS acted as a nucleating agent and increased the crystallinity of the polymer, but the crystallization and melting temperatureswere not affected. The processability of the nanocomposites was improved, observed as an increase in viscosity, storage and loss moduli with respect to the control PCPP, which were deteriorated due to chain scission during recycling. The highest recovery in viscosity and reduction in MFI were found for the hydrophilic NS due to a greater impact of hydrogen bond interactions between the silanol-groups of this NS and the oxidized groups of the PCPP.