INVESTIGADORES
NINAGO mario daniel
congresos y reuniones científicas
Título:
Lithium Naphthalenide Initiators for Controlled Anionic Polymerization
Autor/es:
VERÓNICA A. GONZÁLEZ; ANGEL J. SATTI; MARIO D. NINAGO; ENRIQUE M. VALLÉS; MARCELO A. VILLAR; ANDRÉS E. CIOLINO
Lugar:
Granada
Reunión:
Congreso; EPF 2011, XII GEP Congress, 26th June - 1st July 2011, Granada, Spain; 2011
Resumen:
The use of effective initiators is the key for a successful synthesis of complex macromolecular architectures by anionic polymerization techniques. In this work we report the synthesis and polymerization performance of a soluble initiator obtained by the reaction of naphthalene (Naph) and lithium metal (Li), under mild experimental conditions. Its efficiency was tested in homopolymerization reactions by using different monomers such as styrene (S), isoprene (I) and hexamethyl(cyclotrisiloxane) (D3).
