INVESTIGADORES
GUGLIOTTA Luis Marcelino
artículos
Título:
Parameter Estimation in Emulsion Copolymerization Using Reaction Calorimeter Data
Autor/es:
BARANDIARAN, M.J.; LOPEZ DE ARBINA, L.; DE LA CAL, J.C.; GUGLIOTTA, L.M.; ASUA, J.M.
Revista:
JOURNAL OF APPLIED POLYMER SCIENCE
Editorial:
JOHN WILEY & SONS INC
Referencias:
Lugar: New York; Año: 1995 vol. 55 p. 1231 - 1239
ISSN:
0021-8995
Resumen:
The feasibility of estimating the kinetic parameters of emulsion copolymerization using only calorimetric measurements was investigated by simulation. It was found that for the case in which the average number of radicals per particle exceeds 0.5 only two of the three estimable parameters (ki, ka, and kt) could be estimated together provided that an accurate value for the third parameter is available from independent measurements. For systems with n < 0.5, the three unknown parameters ki, kd, and ka were accurately estimated.
