Layer-by-Layer self-assembled redox polyelectrolytes on passive steel

E. VOLKER; E. J. CALVO; F. J. WILLIAMS

ISRAEL JOURNAL OF CHEMISTRY

SCIENCE FROM ISRAEL-DIVISION OF LASER PAGES PUBL LTD

Lugar: Jerusalem; Año: 2008 vol. 48 p. 305 - 312

0021-2148

Steel samples were passivated in 0.1 M NaOH solutions at 0.3 V vs. Ag/AgCl (3 M KCl) and then poly(allylamine) derivatized with osmium pyridine- bipyridine-chloride complex and poly-(vinylsulfonate) were sequentially self-as- sembled electrostatically layer-by-layer. The resulting electrodes were examined by cyclic voltammetry, ellipsometry, and X-ray Photoelectron Spectroscopy (XPS). These studies demonstrate the formation of a redox polyelectrolyte multilayer onto the passive film protecting the ferrous metal. As the number of deposited polyelec- trolyte layers increases there is an increase in the measured thickness of the self-as- sembled film. The rate of thickness growth in osmium polymer film with the number of deposition cycles is slower for films thinner than ~30 nm. Cyclic voltammetry shows that the electron transfer rate to the outer sphere osmium complex tethered to the polymer backbone is much slower for the multilayer on passive iron than on gold surfaces. This is in agreement with the well-known behavior of soluble redox couples on passive metals and with electrochemical tunelling spectroscopy.