CONICET | Buscador de Institutos y Recursos Humanos

&amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;lt;!-- /* Font Definitions */ @font-face {font-family:Times; panose-1:2 0 5 0 0 0 0 0 0 0; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 0 0 0 1 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-ascii-font-family:Courier; mso-fareast-font-family:Courier; mso-hansi-font-family:Courier; mso-bidi-font-family:"Times New Roman";} @page Section1 {size:612.0pt 792.0pt; margin:72.0pt 90.0pt 72.0pt 90.0pt; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} /* List Definitions */ @list l0 {mso-list-id:295376129; mso-list-type:hybrid; mso-list-template-ids:-34189644 271469648 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} @list l0:level1 {mso-level-start-at:26; mso-level-tab-stop:36.0pt; mso-level-number-position:left; text-indent:-18.0pt; mso-ansi-font-size:12.0pt; font-family:Times; mso-ansi-font-weight:normal; mso-ansi-font-style:normal;} ol {margin-bottom:0cm;} ul {margin-bottom:0cm;} --&amp;amp;amp;amp;amp;amp;amp;amp;amp;amp;gt;Mirna A. Mosiewicki, Piotr Rojek, SławomirMichałowski, Mirta I. Aranguren, Aleksander Prociak, "Rapeseed oil-basedpolyurethane foams modified with glycerol and cellulosemicro/nanocrystals", J. Applied Polymer Science, 132(10) March 10, 2015. artic. No: 41602,doi: 10.1002/app.41602 (1 of 8) &amp;amp;amp;amp;amp;amp;amp;amp;lt;!-- /* Font Definitions */ @font-face {font-family:Times; panose-1:2 0 5 0 0 0 0 0 0 0; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 0 0 0 1 0;} @font-face {font-family:Cambria; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 0 0 0 1 0;} @font-face {font-family:TimesNewRomanPSMT; panose-1:0 0 0 0 0 0 0 0 0 0; mso-font-alt:"Times New Roman"; mso-font-charset:0; mso-generic-font-family:swiss; mso-font-format:other; mso-font-pitch:auto; mso-font-signature:3 0 0 0 1 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin-top:0cm; margin-right:0cm; margin-bottom:10.0pt; margin-left:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-ascii-font-family:Times; mso-fareast-font-family:Cambria; mso-fareast-theme-font:minor-latin; mso-hansi-font-family:Times; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;} @page Section1 {size:612.0pt 792.0pt; margin:72.0pt 90.0pt 72.0pt 90.0pt; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} --&amp;amp;amp;amp;amp;amp;amp;amp;gt; A rapeseed oil-based polyol (ROPO) was synthesized using chemical modification of the rapeseed oil (RO) by epoxidation reaction followed by oxirane ring-opening with diethylene glycol. The ROPO was used in the formulation of low-density green polyurethane (PU) foams. The use of glycerol as hydroxyl component, water as a reactive blowing agent and micro/nanocellulose (MNC) as a reinforcement increases the content of natural components in the formulations with important effects on the final foam properties. The ROPO and their intermediate products are characterized by analytical techniques and FTIR spectroscopy, while the final PU foams are characterized by morphological and mechanical analysis. The results show that the addition of glycerol increases the modulus and yield stress. The incorporation of MNC in small amounts is enough to increase the modulus at low temperatures. Both modifiers cause an increase in water absorption and the fragility of the cell walls, reflected in the micrographs of the foams.

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