Viscosities for binary mixtures of 1-decanol, hexane and diethylamine at 10, 25 and 40 ºC

MIGUEL POSTIGO; ALEJANDRA MARIANO; LELIA MUSSARI; SALVADOR CANZONIERI

JOURNAL OF SOLUTION CHEMISTRY

Plenum Publishing Corporation

Año: 2001 vol. 30 p. 1081 - 1090

0095-9782

xperimental viscosities provide information on the structure of liquids and are required in the design of processes, which involve fluid flow, mass transfer, or heat transfer calculations. This work reports experimental viscosity data of the binary mixtures: 1-decanol + hexane, 1-decanol + diethylamine, and hexane + diethylamine at 10, 25, and 40°C and atmospheric pressure for the whole range of compositions. The viscosities of the pure liquids and their mixtures were determined using Cannon Fenske viscometers thermostated at ±0.01°C. The estimated error in the measured viscosities was less than ±0.005 mPa-s. The dynamic viscosity and the excess energy of activation for viscous flow were also calculated. The equation of Redlich?Kister was used for fitting the excess properties of the binary mixtures. The excess viscosity shows positive deviations from ideal behavior for the mixtures 1- decanol + hexane and 1-decanol + diethylamine and a small negative deviation for the binary system hexane + diethylamine. The experimental results have been also used to test some empirical and semiempirical equations adopted previously to correlate viscosity composition data.