Polypropylene Grafted with Maleic Anhydride: A Stochastic Model.

ROMERO PIETRAFESA, TOMÁS; BRANDOLIN, ADRIANA; SARMORIA, CLAUDIA; ASTEASUAIN, MARIANO

Phoenix, Arizona

Congreso; AIChe Anual Meeting 2022; 2022

AIChe

A Monte Carlo model for the grafting of maleic anhydride (MA) onto polypropylene (PP) considering a large array of reactions was successfully implemented. A good fit to experimental data was obtained. The model allowed obtaining the number- and weight-average molecular weights, degree of grafting, molecular weight distribution (MWD), and detailed information about the grafting distribution. Conclusions about the importance of MA homopolymerization and the length of grafted chains were also obtained. Through the results of a sensitivity analysis, the relative importance of the reactions was assessed.