Selective Synthesis and Molecular Structure of Novel Aminooxyglycosyl Derivatives Bearing Hydroxyphenyl Moieties

LAFUENTE, LETICIA; SANTIAGO, CINTIA C.; ROJAS, AGUSTÍN H.; PIRO, OSCAR E.; ECHEVERRÍA, GUSTAVO A.; PONZINIBBIO, AGUSTÍN

ChemistrySelect

Wiley-Blackwell

Año: 2020 vol. 5 p. 864 - 868

We present the selective synthesis of novel aminooxy glycosyl derivatives bearing hydroxy phenyl moieties. A strict control over the anomeric and E/Z configurations has been achieved. The products obtained are α-glycosides and the aromatic moiety substitute the Schiff´s base trans to the O-glycosidic bond. Single crystal X-ray diffraction and NMR spectral data are reported and analysed.