INVESTIGADORES
VACA CHAVEZ FORNASERO Fabian
artículos
Título:
On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide
Autor/es:
MARCEL BESNARD; ISABEL CABAÇO; FABIAN VACA CHAVEZ; NOËL PINAUD; PEDRO J. SEBASTIÃO; JOÃO A. P. COUTINHO; YANN DANTEN
Revista:
CHEMICAL COMMUNICATIONS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2012 vol. 48 p. 1245 - 1247
ISSN:
1359-7345
Resumen:
The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO2 with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR (1H, 13C, 15N) spectroscopy.