Defective Sr0.9Mo0.9O3-δperovskites with exsolved Ni nanoparticles as high-performance composite anodes for solid-oxide fuel cells

LARRALDE, A.L.; TRONCOSO, L.; ALVAREZ-GALVAN, C.; CASCOS, V.; FERNANDEZ-DÍAZ, M.T.; ALONSO, J.A.

NEW JOURNAL OF CHEMISTRY

ROYAL SOC CHEMISTRY

Año: 2021 vol. 45 p. 12041 - 12049

1144-0546

An A-site deficient perovskite with metallic Ni in exsolution, Ni-Sr0.9Mo0.9O3-δ, has been prepared, characterized and tested as an anode material in intermediate-temperature solid-oxide fuel cells (IT-SOFCs). It was obtained by reduction of a Ni-containing scheelite oxide, from which Ni is segregated to the surface as metal nanoparticles with average size of 30-35 nm, as demonstrated by high-resolution transmission electron microscopy (HR-TEM). An in situ neutron powder diffraction (NPD) study of the Sr0.9Mo0.9O3-δ matrix shows an oxygen deficient cubic perovskite, defined in the Pm3m space group; no crystalline transitions were detected in the tested temperature range up to 850 °C. Morphological observations using a scanning electron microscope (SEM) and pore size determinations by Hg porosimetry showed a highly porous material with macropores. The electrical conductivity gave a maximum value of 215 S cm-1 at 850 °C. A suitable thermal expansion coefficient, with values close to that of the electrolyte, showed no abrupt changes in its slope. Polarization curves and electrochemical impedance spectra (EIS) under open circuit were investigated. In single-cell tests, the materials generated outstanding output powers close to 1025 mW cm-2 at 850 °C using pure H2 as fuel. All these features make this novel A-deficient perovskite with exsolved Ni particles a perfect candidate as anode material in intermediate-temperature SOFCs (IT-SOFCs).