A dynamic analysis of the aluminum titanate (Al2TiO5) reaction-sintering from alumina and titania, properties and effect of alumina particle size

VIOLINI, MARÍA A.; HERNÁNDEZ, MARÍA F.; CONCONI, MARÍA S.; SUÁREZ, GUSTAVO; RENDTORFF, NICOLÁS M.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY

SPRINGER

Año: 2021 vol. 143 p. 95 - 111

1388-6150

Aluminum titanate Al2TiO5 materials were successfully processed from diferent fne commercial powders and characterized.Particularly, two calcined aluminas were compared through a multitechnique approach including diferential thermal analysisand dilatometry together with structural, microestructural, and mechanical characterization. This allowed the description of allthe thermochemical processes during thermal treatment. Developed phases were established. Relatively dense ceramics wereobtained, and complex microstructures were described with interlocked grains and an interconnected microcrack matrix thatdo not jeopardize the material integrity. Multistep sintering and reaction sintering processes were observed in both samples.The frst stage consists of the sintering of the starting powders (alumina and titania). A second sintering stage of the startingpowders was observed for both samples as well. Once advanced, the second one is overlapped with Al2TiO5 formation thatstarts at 1380 °C and fnishes at 1440 °C. They afect crack development and, in consequence, the thermal behavior. Thelower alumina particle size enhances the sintering and reaction advance processes. In the technological temperature range(room temperature?1000 °C), low or even negative thermal expansion behaviors were observed in the developed materials.This, together with the mechanical behavior, encourages structural applications with high thermomechanical solicitationsof Al2TiO5 based materials.