CO2 capture using MEA aqueous solution: Modeling and optimization of the solvent regeneration and CO2 desorption process

PATRICIA MORES; SERGIO MUSSATI; NICOLÁS SCENNA

ENERGY

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2012 vol. 45 p. 1042 - 1058

0360-5442

This paper deals with the simultaneously optimization of operating conditions (pressures, temperatures and flow-rates) and dimensions (diameter and height) of the amine regeneration unit in the post-combustion CO2 capture process. The proposed model takes into account the effect of kinetic reactions on the mass transfer, the hydraulics of the random packing and the pressure drop along the regeneration column. In addition, profiles of temperature, composition and flow-rate along the height of the regenerator are also predicted. The resulting mathematical model is implemented into the optimization environment GAMS (General Algebraic Modeling System) which is a high-level modeling system for mathematical programming and optimization. The benefits of the mathematical programming techniques (equation oriented) are exploited for the simultaneous optimization not only of the operating conditions but also the dimensions of the all piece of equipments (heat exchangers, regeneration unit, condenser and reboiler as well). The mathematical model was successfully verified by comparison of the obtained results with published experimental data and simulated solutions obtained by a process simulator (HYSYS). Once validated, the model was used for optimization purpose. Finally, in order to study the effect of the main process parameters on the optimized results a sensitivity analysis is also investigated and discussed in detail.