INVESTIGADORES
DORN Viviana
artículos
Título:
A new and efficient methodology for olefin epoxidation catalyzed by supported cobalt nanoparticles
Autor/es:
ROSSI-FERNÁNDEZ, LUCÍA; DORN, VIVIANA; RADIVOY, GABRIEL
Revista:
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Editorial:
BEILSTEIN-INSTITUT
Referencias:
Año: 2021 vol. 17 p. 519 - 526
ISSN:
1860-5397
Resumen:
A new heterogeneous catalytic system consisting of cobalt nanoparticles (CoNPs) supported on MgO and tert-butyl hydroperoxide(TBHP) as oxidant is presented. This CoNPs@MgO/t-BuOOH catalytic combination allowed the epoxidation of a variety of olefinswith good to excellent yield and high selectivity. The catalyst preparation is simple and straightforward from commercially availablestarting materials and it could be recovered and reused maintaining its unaltered high activity.
